Publications

2021
78. Corbin, D. A.; Puffer, K. O.; Chism, K. A.; Cole, J. P.; Theriot, J. C.; McCarthy, B. G.; Buss, B. L.; Lim, C. H.; Lincoln, S. R.; Newell, B. S.; Miyake, G. M.; "Radical Addition to N,N-Diaryl Dihydrophenazine Photoredox Catalysts and Implications in Photoinduced Organocatalyzed Atom Transfer Radical Polymerization" Macromolecules, DOI: 10.1021/acs.macromol.1c00501
77. Corbin, D. A.; McCarthy, B. G.; van de Lindt, Z.; Miyake, G. M.; "Radical Cations of Phenoxazine and Dihydrophenazine Photoredox Catalysts and Their Role as Deactivators in Organocatalyzed Atom Transfer Radical Polymerization" Macromolecules, DOI: 10.1021/acs.macromol.1c00640
76. Lattke, Y. M.; Corbin, D. A.; Sartor, S. M.; McCarthy, B. G.; Miyake, G. M.; Damrauer, N. H.; "Interrogation of O-ATRP Activation Conducted by Singlet and Triplet Excited States of Phenoxazine Photocatalysts" J. Phys. Chem. A, DOI: 10.1021/acs.jpca.1c00855

75. Swisher, N. A.; Corbin, D. A.; Miyake, G. M.; "Synthesis, Characterization, and Reactivity of N-Alkyl Phenoxazines in Organocatalyzed Atom Transfer Radical Polymerization" ACS Macro Lett., DOI: 10.1021/acsmacrolett.1c00055

74. Foster, K. E. O.; Jones, R.; Miyake, G. M.; Srubar, W. V.; "Mechanics, optics, and thermodynamics of water transport in chemically modified transparent wood composites" Compos. Sci. Technol., DOI: 10.1016/j.compscitech.2021.108737
2020

73. McCarthy, B. G.; Sartor, S. M.; Cole, J. P.; Damrauer, N. H.; Miyake, G. M.; "Solvent Effects and Side Reactions in Organocatalyzed Atom Transfer Radical Polymerization for Enabling the Controlled Polymerization of Acrylates Catalyzed by Diaryl Dihydrophenazines" Macromolecules, DOI: 10.1021/acs.macromol.0c02245


72. Boyle, B. M.; Collins, J. L.; Mensch, T. E.; Ryan, M. D.; Newell, B. S.; Miyake, G. M.; "Impact of backbone composition on homopolymer dynamics and brush block copolymer self-assembly" Polym. Chem., DOI: 10.1039/D0PY01007C

71. Chen, D. F.; Bernsten, S; Miyake, G. M.; "Organocatalyzed Photoredox Radical Ring-Opening Polymerization of Functionalized Vinylcyclopropanes" Macromolecules, DOI: 10.1021/acs.macromol.0c01367

70. Cole, J. P.; Chen, D. F.; Kudisch, M.; Pearson, R. M.; Lim, C. H.; Miyake, G. M.; "Organocatalyzed Birch Reduction Driven by Visible Light" J. Am. Chem. Soc., DOI: 10.1021/jacs.0c05899.

Pre-print version: "Organocatalyzed Birch Reduction Driven by Visible Light" ChemRxiv, DOI: 10.26434/chemrxiv.11860221

69. Corbin, D.A.; McCarthy, B. G.; Miyake, G. M.; "Impacts of Performing Electrolysis During Organocatalyzed Atom Transfer Radical Polymerization" Polym. Chem., DOI: 10.1039/D0PY00643B

 

68. Abera, G.; Woldeyes, B.; Demash, H. D.; Miyake, G. M.; "The effect of plasticizers on thermoplastic starch films developed from the indigenous Ethiopian tuber crop Anchote (Coccinia abyssinica) starch" Int. J. Biol. Macromol., DOI: 10.1016/j.ijbiomac.2020.03.218

 

67. Liu, B.; Elder, Z. W.; Miyake, G. M.; "Scalable and Phosphine-Free Conversion of Alcohols to Carbon-Heteroatom Bonds through Blue-Light Promoted Iodination Reaction" J. Org. Chem., DOI: 10.1021/acs.joc.9b03373

66. Chen, D. F.; Chrisman, C. H.; Miyake, G. M.; "Bromine Radical Catalysis by Energy Transfer Photosensitization" ACS Catal., DOI: 10.1021/acscatal.0c00281

65. Sartor, S. M.; Chrisman, C. H.; Pearson, R. M.; Miyake, G. M.; Damrauer, N. H.; "Designing High Triplet Yield Phenothiazine Donor-Acceptor Complexes for Photoredox Catalysis" J. Phys. Chem. A, DOI: 10.1021/acs.jpca.9b10400

64. Buss, B.; Lim, C. H.; Miyake, G. M.; "Dimethyl‐dihydroacridines as Photocatalysts in the Organocatalyzed Atom Transfer Radical Polymerization of Acrylate Monomers" Angew. Chem. Int. Ed., DOI: 10.1002/anie.201910828

 

63. Liu, B.; Alegre-Requena, J.; Paton, R.; Miyake, G. M.; "Unconventional Reactivity of Ethynylbenziodoxolone (EBX) Reagents and Thiols: Scope and Mechanism" Chem. Eur. J., DOI: 10.1002/chem.201904520

2019

62. Kudisch, M.; Lim, C. H.; Thordarson, P.; Miyake, G. M.; "Energy Transfer to Ni-amine Complexes in Dual Catalytic, Light-driven C–N Cross-Coupling Reactions" J. Am. Chem. Soc., DOI: 10.1021/jacs.9b11049

 

61. Abera, G; Woldeyes, B.; Demash, H. D.; Miyake, G. M.; "Comparison of physicochemical properties of indigenous Ethiopian tuber crop (Coccinia abyssinica) starch with commercially available potato and wheat starches" Int. J. Biol. Macromol, DOI: 10.1016/j.ijbiomac.2019.08.118

60. Boyle, B. M.; Xiong, P. T.; Mensch, T. E.; Werder, T. J.; Miyake, G. M.; "3D Printing Using Powder Melt Extrusion" Addit. Manuf., DOI: 10.1016/j.addma.2019.100811

59. Chen, D. F.; Boyle, B. M.; McCarthy, B. G.; Lim, C. H.; Miyake, G. M.; "Controlling Polymer Composition in Organocatalyzed Photoredox Radical Ring-Opening Polymerization of Vinylcyclopropanes" J. Am. Chem. Soc., DOI: 10.1021/jacs.9b07230

58. Foster, Kyle E. O.; Hess,Kristen M.; Miyake, G. M.; Srubar III, Wil V.; "Optical Properties and Mechanical Modeling of Acetylated Transparent Wood Composite Laminates" Materials, DOI: 10.3390/ma12142256

57. Sartor, S. M.; Lattke, Y. M.; McCarthy, B. G.; Miyake, G. M.; Damrauer, N. H.; "Effects of Naphthyl Connectivity on the Photophysics of Compact Organic Charge-Transfer Photoredox Catalysts" ‎J. Phys. Chem. A, DOI: 10.3390/ma12142256

56. Boyle, B. M.; Heinz, O.; Miyake, G. M.; Ding, Y; "Impact of the Pendant Group on the Chain Conformation and Bulk Properties of Norbornene Imide-Based Polymers" ‎Macromolecules, DOI: 10.1021/acs.macromol.9b00020

55. Corbin, D. A.; Lim, C. H.; Miyake, G. M.; "Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts" ‎Aldrichimica Acta.

54. Cole, J. P.; Federico, C. R.; Lim, C. H.; Miyake, G. M.; "Photoinduced Organocatalyzed Atom Transfer Radical Polymerization Using Low ppm Catalyst Loading" ‎Macromolecules, DOI: 10.1021/acs.macromol.8b02688

2018

53. Wu, C.; Corrigan, N.; Lim, C. H.; Jung, K.; Zhu, J.; Miyake, G. M.; Xu, J.; Boyer, C. "Guiding the Design of Organic Photocatalyst for PET-RAFT Polymerization: Halogenated Xanthene Dyes" ‎Macromolecules, DOI: 10.1021/acs.macromol.8b02517

52. Rao, H.; Lim, C. H.; Bonin, J.; Miyake, G. M.; Robert, M. "Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst" ‎J. Am. Chem. Soc., DOI: 10.1021/jacs.8b09740

51. Dolinski, N. D.; Page, Z. A.; Discekici, E. H.; Meis, D.; Lee, I.; Jones, G. R.; Whitfield, R.; Pan, X.; McCarthy, B. G.; Shanmugam, S.; Kottisch, V.; Fors, B. P.; Boyer, C.; Miyake, G. M.; Matyjaszewski, K.; Haddleton, D. M.; Alaniz, J. R.; Anastasaki, A.; Hawker, C. J."What happens in the dark? Assessing the temporal control of photo‐mediated controlled radical polymerizations" ‎J. Polym. Sci. A, DOI: 10.1002/pola.29247

50. Liu, B.; Lim, C. H.; Miyake, G. M."Light driven intermolecular charge transfer induced reactivity of ethynylbenziodoxol(on)e (EBX) and phenols" J. Am. Chem. Soc., DOI: 10.1021/jacs.8b05870

49. Liu, B.; Lim, C. H.; Miyake, G. M. "Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer" Synlett, DOI: 10.1055/s-0037-1610230

48. McCarthy, B.; Miyake, G. M. "Organocatalyzed Atom Transfer Radical Polymerization Catalyzed by Core Modified N-Aryl Phenoxazines Performed under Air" ACS. Macro Lett., DOI: 10.1021/acsmacrolett.8b00497

47. Buss, B. L.; Miyake, G. M."Photoinduced controlled radical polymerizations performed in flow: methods, products, and opportunities" Chem. Mater., DOI: 10.1021/acs.chemmater.8b01359

46. Lim, C. H.; Kudisch, M.; Liu, B. Miyake, G. M."C-N Cross-Coupling via Photoexcitation of Nickel-Amine Complexes" J. Am. Chem. Soc., DOI: 10.1021/jacs.8b03744

45. Theriot, J. C.; Miyake, G. M.; Boyer, C. A. "N,N-Diaryl Dihydrophenazines as Photoredox Catalysts for PET-RAFT and Sequential PET-RAFT/O-ATRP" ACS Macro Lett., DOI: 10.1021/acsmacrolett.8b00281

44. Sartor, S. M.; McCarthy, B. G.; Pearson, R. M.; Miyake, G. M.; Damrauer, N. H. "Exploiting Charge-Transfer States for Maximizing Intersystem Crossing Yields in Organic Photoredox Catalysts" J. Am. Chem. Soc., DOI: 10.1021/jacs.8b01001

43. McCarthy, B. G.; Pearson, R. M.; Lim, C. H.; Sartor, S. M.; Damrauer, N. H.; Miyake, G. M.""Structure–Property Relationships for Tailoring Phenoxazines as Reducing Photoredox Catalysts" J. Am. Chem. Soc., DOI: 10.1021/jacs.7b12074

42. Learsch, R.; Miyake, G. M. "Arm-first synthesis of star polymers with polywedge arms using ring-opening metathesis polymerization and bifunctional crosslinkers" J. Polym. Sci. A, DOI: 10.1002/pola.28946


 2017

41. Buss, B. L.; Beck, L. R.; Miyake, G. M. "Synthesis of Star Polymers Using Organocatalyzed Atom Transfer Radical Polymerization Through a Core-first Approach" Polym. Chem., DOI: 10.1039/C7PY01833A

40. Liu, B.; Lim, C. H.; Miyake, G. M. "Visible-Light-Promoted C–S Cross-Coupling via Intermolecular Charge TransferJ. Am. Chem. Soc., DOI: 10.1021/jacs.7b07390

39. Boyer, C. A.; Miyake, G. M. "Polymers and Light" Macromol. Rapid Commun., DOI:10.1002/marc.201700327

38. Du, Y.; Pearson, R. M.; Lim, C. H.; Sartor, S. M.; Ryan, M. D.; Yang, H.; Damrauer, N. H.; Miyake, G. M. "Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious MetalsChem. Eur. J.DOI:10.1002/chem.201702926

37. Ryan, M. D.; Pearson, R. M.; French, T. A.; Miyake, G. M. "Impact of Light Intensity on Control in Photoinduced Organocatalyzed Atom Transfer Radical PolymerizationMacromolecules, DOI:10.1021/acs.macromol.7b00502

36. Rapf, R. J.; Perkins, R. J.; Yang, H.; Miyake, G. M.; Carpenter, B. K.; Vaida, V. "Photochemical Synthesis of Oligomeric Amphiphiles from Alkyl Oxoacids in Aqueous EnvironmentsJ. Am. Chem. Soc.DOI: 10.1021/jacs.7b01707

35. Theriot, J. C.; McCarthy, B. G.; Lim, C. H.; Miyake, G. M. "Organocatalyzed Atom Transfer Radical Polymerization: Perspectives on Catalyst Design and Performance" Macromol. Rapid Commun., DOI:10.1002/marc.201700040

34. Ramsey, B. L.; Pearson, R. M.; Beck, L. R.; Miyake, G. M. "Photoinduced Organocatalyzed Atom Transfer Radical Polymerization Using Continuous Flow" Macromolecules, DOI: 10.1021/acs.macromol.6b02791

33. Ryan, M. D.; Theriot, J. C.; Lim, C. H.; Yang, H.; Lockwood, A. G.; Garrison, N. G.; Lincoln, S. R.; Musgrave, C. B.; Miyake, G. M. "Solvent effects on the intramolecular charge transfer character of N,N‐diaryl dihydrophenazine catalysts for organocatalyzed atom transfer radical polymerization" J. Polym. Sci. Part A: Polym. Chem., DOI:10.1002/pola.28574

32. Boyle, B. M.; French, T. A.; Pearson, R. M.; McCarthy, B. G.; Miyake, G. M. "Structural Color for Additive Manufacturing: 3D-Printed Photonic Crystals from Block Copolymers" ACS Nano., DOI:10.1021/acsnano.7b00032

31. Lim, C. H.; Ryan, M. D.; McCarthy, B. G.; Theriot, J. C.; Sartor, S. M.; Damrauer, N. H.; Musgrave, C. B.; Miyake, G. M. "Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization" J. Am. Chem. Soc., DOI:10.1021/jacs.6b11022


2016

30. Pearson, R. M.; Lim, C. H.; McCarthy, B. G.; Musgrave, C. B.; Miyake, G. M. "Organocatalyzed Atom Transfer Radical Polymerization Using N‑Aryl Phenoxazines as Photoredox Catalysts" J. Am. Chem. Soc., DOI: 10.1021/jacs.6b08068

29. Theriot, J. C.; Lim, C. H.; Yang, H.; Ryan, M. D.; Musgrave, C. B.; Miyake, G. M. "Organocatalyzed atom transfer radical polymerization driven by visible light" Science, DOI:10.1126/science.aaf3935

28. Guzmán, P. E.; Piunova, V. A.; Miyake, G. M.; Grubbs, R. H. "Synthesis and Ring-Opening Metathesis Polymerization of Second-Generation Dendronized Poly(ether) Monomers Initiated by Ruthenium Carbenes" Oil Gas Sci. Technol., DOI: 10.2516/ogst/2015042

27. Theriot, J. C.; Ryan, M. D.; French, T. A.; Pearson, R. M.; Miyake, G. M. "Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst" J. Vis. Exp., DOI:10.3791/53571


2015

26. Aluculesei, A.; Pipertzis, A.; Piunova, V. A.; Miyake, G. M.; Floudas, G.; Fytas, G.; Grubbs, R. H. "Thermomechanical Behavior and Local Dynamics of Dendronized Block Copolymers and Constituent Homopolymers" Macromolecules, DOI: 10.1021/acs.macromol.5b00779

25. Estrada, J.; Woen, D. H.; Tham, F. S.; Miyake, G. M.; Lavallo, V.  "Synthesis and Reactivity of a Zwitterionic Palladium Allyl Complex Supported by a Perchlorinated Carboranyl Phosphine" Inorg. Chem. DOI: 10.1021/acs.inorgchem.5b00576

24. Miyake, G. M.; Zhang, Y.; Chen, E. Y.-X. "Polymerizability of Exo-Methylene-Lactide Toward Vinyl Addition and Ring Opening" J. Poly. Sci. Part A: Polym. Chem. DOI: 10.1002/pola.27629


2014

23. Miyake, G. M.; Theriot, J. C. "Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light" Macromolecules, DOI: 10.1021/ma502044f

 


22. Chang, A. B.; Miyake, G. M.; Grubbs, R. H. "Sequence-Controlled Polymers by Ruthenium-Mediated Ring-Opening Methathesis Polymerization" ACS Symposium Series 2014, 1170, 161-188.

21. Daeffler, C. S.; Miyake, G. M.; Li, J.; Grubbs, R. H. "Partial Kinetic Resolution of Oxanorbornenes by Ring-Opening Metathesis Polymerization with a Chiral Ruthenium Initiator" ACS Macro Lett. 2014, 3, 102-104.

20. Sveinbjornsson, B. R.; Miyake, G. M.; El-Batta, A.; Grubbs, R. H. "Stereocomplex Formation of Densely Grafted Brush Polymers" ACS Macro Lett. 2014, 3, 26-29.

19. Miyake, G. M.; Akhtar, M. N.; Fazal, A.; J. E. A.; Daeffler, C. S.; Grubbs, R. H. "Chelating N-Heterocyclic Carbene Group IV Complexes for the Polymerization of Ethylene and Styrene" J. Organomet. Chem. 2013, 728, 1-5.

18. Piunova, V. A.; Miyake, G. M.; Daeffler, C. S.; Weitekamp, R. A.; Grubbs, R. H. "Highly-Ordered Dielectric Mirrors via the Self-Assembly of Dendronized Block Copolymers" J. Am. Chem. Soc. 2013, 135, 15609-15616.

17. Miyake, G. M.; Piunova, V. A.; Weitekamp, R. A.; Grubbs, R. H. "Precisely Tunable Photonic Crystals From the Rapid Self-Assembly of Brush Block Copolymer Blends" Angew. Chem., Int. Ed. Engl. 2012, 51, 11246-11248.

16. Miyake, G. M.; Weitekamp, R. A.; Piunova, V. A.; Grubbs, R. H. "Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals" J. Am. Chem. Soc. 2012, 134, 14249-14254.

15. Sveinbjörnsson, B. R.; Weitekamp, R. A.; Miyake, G. M.; Xia, Y.; Atwater, H. A.; Grubbs, R. H. "Rapid Self-Assembly of Brush Block Copolymers to Photonic Crystals" P. Natl. Acad. Sci. USA 2012, 109, 14332-14336.

14. Zhang, Y.; Miyake, G. M.; John, M., G.; Falivene, L.; Caporaso, L.; Cavallo, L.; Chen, E. Y.-X. "Lewis Pair Polymerization by Classical and Frustrated Lewis Pairs: Acid, Base and Monomer Scope and Polymerization Mechanism" Dalton Trans. 2012, 41, 9119-9134.

13. Hu, Y.; Miyake, G. M.; Wang, B.; Cui, D.; Chen, E. Y.-X. "Ansa-Rare-Earth Metal Catalysts for Rapid and Stereoselective Polymerizations of Renewable Methylene Methylbutyrolactones" Chem. Eur. J. 2011, 18, 3345-3354.

12. Miyake, G. M.; Iida, H.; Hu, H.-Y.; Tang, Z.; Chen, E. Y.-X.; Yashima, E. "Synthesis of Helical Poly(phenylacetylene)s Bearing Cinchona Alkaloid Pendants and Their Application to Asymmetric Organocatalysis" J. Polym. Sci. Part A: Polym. Chem. 2011, 49, 5192-5198.

11. Miyake, G. M.; Chen, E. Y.-X. "Synthesis of Highly Syndiotactic Polymers by Discrete Catalysts or Initiators" Polym. Chem. 2011, 2, 2462-2480.

10. Miyake, G. M.; Chen, E. Y.-X. "Cinchona Alkaloids as Stereoselective Organocatalysts for the Partial Kinetic Resolution Polymerization of rac-Lactide" Macromolecules 2011, 44, 4116-4124.

9. Zhang, Y.; Miyake, G. M.; Chen, E. Y.-X. "Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones to High Molecular Weight Polymers" Angew. Chem., Int. Ed. Engl. 2010, 49, 10158-10162.

8. Miyake, G. M.; DiRocco, D.; Oberg, K. M.; Liu, Q.; Bayram, E.; Finke, R. G.; Rovis, T.; Chen, E. Y.-X. "Stereospecific Polymerization of Chiral Oxazolidinone-Functionalized Alkenes" Macromolecules 2010, 43, 7504-7514.

7. Miyake, G. M.; Newton, S. E.; Mariott, W. R.; Chen, E. Y.-X. "Coordination Polymerization of Renewable Butyrolactone-Based Vinyl Monomers by Lanthanide and Early Metal Catalysts" Dalton Trans. 2010, 39, 6710-6718.

6. Miyake, G. M.; Zhang, Y.; Chen, E. Y.-X. "Living Polymerization of Naturally Renewable Butyrolactone-Based Vinylidene Monomers by Ambiphilic Silicon Propagators" Macromolecules 2010, 43, 4902-4908.

5. Del Villano, L.; Kelland, M.; Miyake, G. M.; Chen, E. Y.-X. "Effect of Polymer Tacticity on the Performance of Poly(N,N-Dialkylacrylamide)s as Kinetic Hydrate Inhibitors" Energy Fuels 2010, 24, 2554-2562.

4. Miyake, G. M.; Caporaso, L.; Cavallo, L.; Chen, E. Y.-X. "Coordination-Addition Polymerization and Kinetic Resolution of Methacrylamides by Chiral Metallocene Catalysts" Macromolecules 2009, 42, 1462-1471.

3. Miyake, G. M.; Chen, E. Y.-X. "Metallocene-Mediated Asymmetric Coordination Polymerization of Polar Vinyl Monomers to Optically Active, Stereoregular Polymers" Macromolecules 2008, 41, 3405-3416.

2. Miyake, G. M.; Mariott, W. R.; Chen, E. Y.-X. "Asymmetric Coordination Polymerization of Acrylamides by Enantiomeric Metallocenium Ester Enolate Catalysts" J. Am. Chem. Soc. 2007, 129, 6724-6725.

1. Brochu, M.; Gauntt, B. D.; Shah, R.; Miyake, G.; Loehman, R. E. "Comparison Between Barium and Strontium-Glass Composites for Sealing SOFCs" J. Eur. Ceram. Soc. 2006, 26, 3307-3313.

Book Chapters

2. Ryan, M. D.; Pearson, R. M.; Miyake, G. M. "Organocatalyzed Controlled Radical Polymerizations" Organic Catalysis for Polymerisation. 2018, 584-606.

1. Miyake, G. M.; Weitekamp, R. A.; Grubbs, R. H. "Synthesis of Materials with Nanostructured Periodicity" Handbook of Metathesis Vol. 3: Polymer Synthesis, Second Edition. 2015, 93-113.